Magic Milk

Magic Milk

IMG_6084I did this video for my granddaughter Sophie who lives too far away to see as much as I would like. The chemistry behind the moving colour is fascinating but I’ll leave that for now.

Savage Garden, attack of the killer ladybirds

Savage Garden, attack of the killer ladybirds

aphidladybirdA tale of life and death in the garden as aphids and lady birds battle for survival in the hot summer sun on their swan plant universe. Resources are at a premium. The swan plant starts the food chain and it all ends horribly for aphids. Aphids, ladybirds, ladybird larvae and caterpillars are unaffected by the deadly cardenolide glycosides stockpiled in swan plant leaves as a chemical deterrent to predators.

Savage Garden, attack of the killer wasps

Savage Garden, attack of the killer wasps

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Chemical warfare in the garden,

Early summer and dark chemical processes are at work in the bright sunlight. Swan plants are producing and stockpiling deadly molecules in their sap and leaves. A chemical defence system designed to kill insects foraging for food.  The main components of this molecular arsenal are cardenolide glycosides, steroids with an attached sugar structure. These toxins can induce cardiac arrest.

Monarch caterpillars and butterflies are immune to these poisons. Caterpillars voraciously devour swan plant leaves. In the process they hijack the plant’s chemical defence system for use against predators. Birds associate becoming sick with a diet of brightly coloured caterpillars or butterflies and drop them from their diet.

Attack of the killer wasps.

Asian paper wasps are very determined predators of monarch caterpillars and are unaffected by the cardenolides. Wasps need protein for nest construction and developing larvae in spring and early summer. Caterpillars are a good source of protein at this stage.  

I watched wasps make their way through dense foliage in relentless pursuit of their prey. Monarch caterpillars appear to understand the danger and some seek refuge amongst the spines of the swan plant seed pods. The aerial bombardment is relentless and a plant can be completely stripped of the caterpillar population in a day. The big mature caterpillars are a favourite target and I have seen them stand up on a leaf in a forlorn attempt to beat off a merciless attacker.

The assault has a number of stages

  • The wasp lands on the caterpillar and probably stings it
  • The wasp starts to skin the caterpillar while it is still moving. It bites through the skin which rolls back to reveal the underlying body.
  • It may move the whole carcass to a more stable location where it slices it up into manageable chunks to fly away with.

In late summer when the need for protein has diminished, wasps change their diet, feasting instead on the nectar produced by swan plant flowers.

For more information on cardenolide concentrations and effect on predators.

Relationship beteeen steroids and cardenolide glycosides

oleandrin a cardenolide glycoside

oleandrin a cardenolide glycoside

 Oleandrin is one of the cardenolide glycosicdes found in swan plants. The structure hanging on to the bottom left of the steroid skeleton is based on a sugar unit hence the glycoside in the name.

 

Hydrocarbons to die for, an inconvenient truth for Prime Minister John Key

Hydrocarbons to die for, an inconvenient truth for Prime Minister John Key

Hydrocarbons are found in oil. We burn them polymerise them turn them into pharmaceuticals paints explosives and plastics. Virtually everything not made of wood, animal skins, stone or metal has oil at its source. Crude oil and gas are important to our society but what costs are we prepared to pay to maintain supplies? I watched John Key on the TV programme Campbell live this evening. He appeared to be softening us up, manufacturing consent so that we are happy to let loose our rats of war. We’ll hold back the full sized dogs because after all New Zealand is a small country. The justification used by Mr Key ( Prime Minister New Zealand) was the need to intervene and stop savage beheadings carried out by ISIS. He argued that New Zealanders would probably support a military intervention and he may be right.

We should be clear about our objectives in this endeavour. I want assurance from my Government that any future military involvement in this region has nothing to do with protecting oil pipelines and the hydrocarbons that flow through them.

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  • Iraq has large productive oilfields
  • There are huge oil reserves, the prospective structures on the maps
  • There are vulnerable oil pipelines.

Transparency and honesty around objectives for military involvement is essential for informed consent in a democratic process.

The Campbell Live programme on TV3 is a breath of fresh air on New Zealand issues. It is time to apply your undoubted investigative talents to the international scene.

 

 

 

 

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1080 poison use in New Zealand: Why we have badly let down two Reefton women caught in a toxic 1080 aerial dump.

1080 poison use in New Zealand: Why we have badly let down two Reefton women caught in a toxic 1080 aerial dump.

Dropped on people in New Zealand

Dropped on people in New Zealand

I have just watched the Campbell Live programme. It contained a report on problems suffered by two Reefton women caught in the bush as 1080 poison rained from the sky last summer(NZ Herald).

1080 is highly toxic to mammals and insects. It disrupts our biology. in particular a complex process known as the Krebs cycle which releases energy to keep cells alive. Once 1080 molecules enter a cell they rapidly stop the Krebs cycle dead.

It follows that body organs with high energy needs, in particular the brain, heart and lungs are at risk. Exposure to 1080 could damage organs without being fatal. This is euphemistically referred to as a sublethal dose. You won’t drop dead on the spot but you may be damaged for the rest of your life. My concern with the situation reported is that inhalation of dust could have delivered a sub lethal but potentially harmful dose of 1080.

What about people who work in the 1080 industry? How are they protected from this highly toxic material as they formulate and deliver the deadly green pellets. They are protected by regulations which require them to take precautions.

Quoting from The Use of 1080 for pest control (July 2004 a discussion document) Procedures and Standard for use.

“Strict codes of practice require that appropriate protective protective clothing is worn by all those involved in the manufacture and handling of 1080.

“Under these procedures wearing protective equipment such as gloves and overalls is compulsory when handling 1080 in bulk. Respirators and eye protection are also required when handling 1080 in large quantities such as during aerial operations.”

Which brings me to why I think we have let sisters  Gwen Gardner and Kathleen Bartlett from Reefton down. Great caution is required to ensure minimal contact with 1080. Dropping a bucket load on unsuspecting picnickers is an unforgivable error. If you can’t guarantee the absence of humans in the drop zone then you shouldn’t drop. Relying on a few inadequate signs is morally unacceptable and criminally negligent.

 

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